05/23/2007
Hot Ice
A few weeks ago (5/2/2007), I wrote about the discovery of a planet termed “super-Earth” orbiting Gliese 581, a red dwarf star. This past week, the same team of Swiss-based astronomers announced another planet orbiting another red dwarf star 33 light-years from Earth. As opposed to super-Earth, which may be a candidate for hosting some form of life, the newly announced planet seems way too hot for any life as we know it. This is a Neptune-size planet that whips around its star, GJ 436b, in only 3 days and sports toasty temperatures approaching 250 degrees Centigrade (about 470 degrees Fahrenheit). Its discovery was a lucky one in that its orbit carries it between its star and our Earth. The researchers could observe the decrease in the amount of light from the star when the planet passed across the face of the star. From the decrease in the amount of starlight, they could calculate the diameter of the planet and, I’m assuming, from the orbit of the planet and the mass of the star they could calculate the mass of the planet.
The surprise came when the mass turned out to be consistent with the planet being mostly hot solid water – ice! Of course, my natural tendency was to think these guys and/or gals are out of their mind. How can ice exist on such a hot body with temps way above the boiling point of water? Then I read an article on the discovery by Maggie Fox posted on the Scientific American Web site. The reason that ice can exist at such temperatures is that the pressures on this Neptune-size planet are quite high. This didn’t seem right when I recalled that I’ve heard that the reason ice skaters glide so smoothly across the ice is that the weight of the skater on the thin blades is sufficient to melt the ice under the skates. In other words, increasing the pressure lowers the freezing/melting point of water/ice. Hence, the slippery skating. But if pressure lowers the melting point of ice what about that high-pressure hot planet? Clearly, I had to look more deeply into the subject.
Accordingly, I turned to my shopworn 1944 edition of my battered physical chemistry textbook by Frederick Getman and Farrington Daniels. Sure enough, on page 157 (heavily underlined by me in 1945), is a calculation using an equation derived by a fellow named Clapeyron back in 1834. The equation shows that the effect of pressure on the melting point of ice depends on the heat needed to melt the ice and on the volume change when water freezes to form ice. Those of us old enough to have had our milk delivered in bottles know that water increases in volume when it freezes, as witnessed by the milk pushing the cap off the top of the milk bottle when left outside in freezing weather.
The Clapeyron calculation says that it takes 133 atmospheres pressure to lower the melting point of ice 1 degree Centigrade. (An atmosphere is about 14.7 pounds per square inch.) But wait a minute. The high pressures on that hot planet should be high enough to lower the melting point significantly, so how can there be any ice? Well, turning to page 311 of my old textbook, I found the key to the answer. At high pressures, in 1944, there were seven different known forms of ice having different crystal structures. All of these high-pressure ices are denser than water, unlike the ordinary ice we skate on or add to our drinks. If water froze to form any of these high-pressure ices, the volume would decrease and the cap would stay on our bottle of milk.
If the volume decreases on freezing, Clapeyron’s equation tells us that the freezing point will increase, not decrease, with increasing pressure. My textbook being over 60 years old, I went online to see if there was anything new in the way of ice. Sure enough, there are now at least 13 or 14 different forms of ice that have been found at high pressures. I found a reference to the existence of one high-pressure ice being solid at 175 degrees Centigrade, way above the boiling point of water (100 degrees Centigrade) and approaching the nearly 250 degree temperatures possible on the planet orbiting GJ 436b. My search was not an exhaustive one and now I’m willing to accept that there is an ice (or ices) that can exist on a toasty hot planet.
Oh, about that ice skating bit, in the course of searching the Web, I encountered conflicting views on the subject. The argument that the pressure of the skate on the ice causes the ice to melt, forming a film of water, seems rather dicey. I looked up the thickness of the typical blade of an ice skate and found that it was about an eighth of an inch for hockey and about half that for speed skating. Taking the hockey example, if the blade is a foot long I calculate it has an area of about 1.4 square inches. For convenience, let’s say our hockey player weighs 140 pounds, a bit light I admit. However, that translates to 140/1.4 = 100 pounds per square inch, or about 7 atmospheres. Remembering that Clapeyron said it takes 133 atmospheres to lower the melting point 1 degree, our hockey player, skating flat on his skate, only lowers the melting point by 7/133 = 0.05 degrees C.
If the temperature of the ice is more than a degree or so below 0 degrees C (32 degrees F) lowering the melting point a degree won’t melt the colder ice. Another urban myth down the drain? Possibly. On the other hand, water is a crazy substance and I’ve seen some work suggesting that, even when water ice is significantly below the freezing point, the surface molecules are more like a liquid than in the solid bulk ice. Even if true, skaters can skate on ice that’s much colder than the melting/freezing point where even those surface molecules ought to be tied down to the rest of the molecule in the ice. Even today, water in both solid and liquid forms is not a done deal and papers on its structure and properties will continue to appear for some time to come.
I just happened to think. What will happen to that hot icy planet? Will it eventually get so close to the red dwarf star that it just evaporates or will it get sucked into the star with its icy core still intact? If the latter, that should be some spectacular explosion when all that hot ice becomes superheated steam!
Allen F. Bortrum
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