Polecats and Other Odiferous Subjects

Polecats and Other Odiferous Subjects

My Webster”s New World Dictionary defines the word “skunk”

thusly: 1. Any of several bushy-tailed mammals (family

Mustelid”) of the New World… and 2. [Colloquial] a

despicable, offensive person. The colloquial definition certainly

fits Osaka bin Laden. I believe that we have been, and still are in

the Chinese Year of the Snake but I would term it the year of the

skunk.

What led me to look up this definition? There was a recent item

in our newspaper about the police in our town capturing a rabid

animal. The article mentioned that we should be wary of any

strangely acting raccoons or skunks. The mention of skunks

brought to mind a couple of memories. One was of my high

school days when some of my more adventurous classmates were

involved in the trapping of these odiferous creatures. Needless to

say, those guys were not welcomed to class after a successful

mission! I may have mentioned before my witnessing a skunk

spraying an unsuspecting lady as she and the skunk encountered

each other when the skunk emerged from behind a wall. Not a

pleasant sight, or smell. If you”re wondering why anyone would

want to trap a skunk, the answer is that the fur of a skunk is

really quite beautiful. Indeed, at one time there were so-called

“Alaskan sable” coats, actually made with skunk fur. Then the

government stepped in and made the manufacturers characterize

the fur a bit more accurately. The skunk fur business hasn”t been

the same since.

Shortly after seeing the news article, I came upon what I thought

were two related articles in the December 2001 issue of the

Smithsonian magazine. One, titled “Skunk Man” was by Steve

Kemper. The other, “Fire and Brimstone” by John Ross, was a

short article with marvelous pictures of sulfur mining in Java.

Now I have to plead guilty to a gross ignorance of my organic

chemistry. Initially, when I started this piece, I thought to tie in

the fact that many sulfur-containing compounds are on the

unpleasant side as far as odor is concerned. Just compare water,

H2O, with hydrogen sulfide, H2S. Replacing that atom of oxygen

in water with an atom of sulfur results in the compound

responsible for the smell of rotten eggs. Hydrogen sulfide can

also kill you if you breathe in too much of it. Which brings back

the memory of my analytical chemistry class, in which we

generated hydrogen sulfide in a lab with minimal exhaust hood

facilities and the lab often reeked of rotten eggs. They say that

you”re in real danger when you stop smelling it.

Back to skunks, I remember our organic chemistry professor

telling us that eau de skunk was beta methyl indole. I”m rather

impressed that after 58 years, I still remember this compound and

its tie-in with the skunk. However, when I began this column, I

thought that the odor of beta methyl indole was due to the fact

that it was a sulfur compound. Fortunately, being a true scientist

and wanting to impress you that I knew the formula, I looked it

up in my Handbook of Chemistry and Physics. I”m mortified.

There”s not a speck of sulfur in the formula! Humiliated, I will

maintain that the article on sulfur mining is still relevant, if only

because the skunk and sulfur mining share a foul smelling,

odiferous nature.

Let”s turn to the “skunk man”, an assistant professor at the

University of New Mexico in Albuquerque by the interesting

name of Jerry Dragoo. Stifle that impulse to rhyme it with Mr.

Magoo! On the other hand, the two do share something in

common, if my memory is correct. They both suffer from a

deficiency in one of their senses, Magoo”s being his rather poor

eyesight. Dragoo”s only became apparent to him relatively late

in life, I would guess in his late teens or early 20s.

He was an undergraduate in college when he developed an

interest in mustelids (Mustelid” in the definition cited in my

opening paragraph). According to my dictionary, the mustelids

are a class of animals that includes weasels, martens, minks and

polecats among others. Polecat is just a fancy term for a skunk.

Dragoo actually was interested in small ferocious mustelids like

minks and wolverines. His professor, however, must have had a

premonition. He asked Dragoo to carry out research on the

spotted skunk. Dutifully, Dragoo went out and trapped a skunk.

As he was making notes and studying the little guy, he noticed a

spray and an oily substance on his notes. You and I now know it

was one of those indoles. Yet, Dragoo never noticed anything

out of the ordinary except that the drizzle of oily stuff came out

of a cloudless sky! It wasn”t until a couple days later, when

Dragoo came back to class and was promptly ejected, that his

sensory deficiency became apparent. He had virtually no sense

of smell! It was obvious that he had found his calling.

As he pursued his studies of skunks on the way to his doctorate,

he broadened his research to other kinds of skunks such as the

hooded and hog-nosed skunks. He also decided it was silly to go

to all the trouble of trapping the critters and adopted the more

straightforward approach of just going out and grabbing them by

the tail! Needless to say, he”s been kicked out of many places,

including apartments, since first discovering his sensory

impediment.

Along the way, Dragoo has actually become a celebrity of sorts

in the mustelid research community. He and a colleague from

Texas A & M, Rodney Honeycut, published a paper in 1997 that

shook up that community. In spite of his somewhat weird

behavior, Dragoo had a serious mission. He wanted to see how

the skunk fit into the evolutionary scheme of things in the

mustelid family. Accordingly, he joined the modern trend of

sequencing genes and came up with a startling conclusion. The

skunks didn”t fit in the mustelid group at all! Dragoo”s idea is

that the North American skunk and what can only be presumed

to be another smelly critter, the Asian stink badger, branched off

millions of years ago to form their own family. If Dragoo is

correct, we all should make a note in our dictionaries and strike

“polecat” from the list of the family Mustelid”.

I have to say something about sulfur since I made the

commitment. The fire and brimstone article is aptly titled,

brimstone being an ancient term for sulfur. The fire alludes to

the Javanese miners who gather the sulfur by descending down

some 700 feet or so into a volcano that is still literally belching

fire and brimstone. These miners use a technique that employs

ceramic pipes to condense the fumes spewing from the volcano.

The fumes condense to form huge stalagmites of sulfur. The

miners go down into the volcano, hack up the deposits of yellow

sulfur into chunks they load in baskets to carry back up to be

unloaded. The place reeks with sulfur dioxide fumes and every

so often the volcano belches out steam mixing in with the other

gases. For two round trips a day into this hellhole, the workers

are paid two dollars, a healthy wage for Java!

It”s worth looking up the article to see the photos of these miners

at work. You”ll appreciate your own line of work much more!

Unless, of course, you”re a fireman or policeman in New York.

Speaking of occupations, one reason I became a chemist is that I

received a chemistry set when I was a kid. My 8-year old

grandson got a chemistry set for Christmas. He being rather

young to go it alone in the world of chemicals, it was agreed that

the set should remain in old Bortrum”s custody and that

experiments should be carried out jointly. Well, I opened the set

and started reading the manual. The environmental/safety people

and probably the lawyers must have written the instructions,

which contain such statements as “TREAT EVERY CHEMICAL

AS THOUGH IT IS THE MOST DEADLY POISON!” Every

container has a WARNING or DANGER label. When I was a

kid, I don”t recall any such emphasis on the hazards involved. I

guess it”s a good idea but hey, after reading the instructions, I”m

not so sure old Dr. Bortrum can handle this chemistry set! After

all, he thought the skunk”s odor was due to sulfur!

Allen F. Bortrum