Thallium and Murder

Thallium and Murder

Next month marks the sixth anniversary of the murder of Nicole

Brown Simpson and Ron Goldman. Normally, I don”t write about

such gruesome events, although some might say that Pfiesteria

going after those fish was pretty rough stuff. At any rate, I was

fascinated by an article in the April 3 issue of Chemical and

Engineering News on a symposium at Pittcon 2000. Pittcon

stands for the Pittsburgh Conference, which of course was held in

New Orleans, but that”s another story. The symposium was titled

“Forensic Chemistry: Pathology, Toxicology, Criminalistics, and

Jurisprudence”. This may sound like a pretty sophisticated kind

of symposium but the cases they discussed were down to earth, to

put it mildly. It occurs to me that one reason that we scientists

seem to enjoy our work so much is that many of the more

interesting scientific problems are like detective stories. Certainly

the searches for a cure for cancer, WIMPs and dark matter and

the ultimate fundamental particle(s) (strings?) qualify as mysteries

of the highest order.

Back to Pittcon, one of the key speakers was Henry Lee, who is,

among other things, director of the Connecticut State Police

Forensic Science Laboratory. You may remember Henry in his

role as a consultant and witness in the O. J. trial and as one of the

world”s foremost criminologists. According to the article, the

case that helped to first establish Lee as a topnotch mystery solver

was the famed “wood chipper murder” case. Yes, it”s a wood

chipper like those used by the tree people and right away you

know this is not going to be pretty. Surprisingly, the perpetrator,

Richard, was a former CIA employee and an airline pilot. His

victim was Helle, his wife and a flight attendant. She disappeared

in November, 1986 after working a flight from Germany to New

York. Henry Lee started his work on the case by noting the

carpet in Richard”s home was gone and there were signs of a

considerable amount of washing. So, it was off to the town dump

for a major dig, not a pleasant task and, furthermore, no rug. But

Lee did find out that Richard had rented a wood chipper and he

managed to latch on to that very same chipper.

But again, no luck. The chipper was clean. However, Lee

learned that someone had seen a man using just such a device

down by a lake during a heavy snowstorm. So it was off to the

lake. There, Lee and his colleagues again dug deep, melting snow

layer by layer. Sure enough, they found small pieces of bone,

hair, polished toenail and other items. DNA tests proved the

bone was from a female (today, the DNA test would probably

have proved a direct match to the victim), some hair was similar

to the victim”s hair and a tooth was identified from dental records

as one of Helle”s teeth.

So, to nail down the case, it was back to the wood chipper. How

to check to see if the bits of bone were indeed formed in the

chipper? Obviously, running a human corpse through the chipper

was not a viable strategy so Lee settled on a dead pig! Sure

enough, the patterns on the pig”s bones were the same as on the

bones buried in the snow. The use of even a dead pig did not set

well with one animal lover, who picketed Lee”s lab for two weeks

after learning of the experiment. Lee, still not satisfied, wanted to

run some hair through the chipper and, anxious to find a suitable

sample, cut off a goodly chunk of his own daughter”s long hair.

Lee”s wife didn”t speak to him for three weeks!

Even then, before the O. J. case, the jury presented a problem.

During the trial, one juror went out for lunch and didn”t bother to

return! Who knows, maybe they were serving chopped ham?

Anyway, after the mistrial, Richard was convicted in a second

trial and is now serving 40 years. While both literal and figurative

persistent digging solved this case, the science seems to me to be

relatively straightforward, albeit not very tidy.

Another, more sophisticated murder, was described at the

symposium by forensic toxicologist Frederic Rieders. The victim,

Robert, died in the Hershey Medical Center in September of

1991. When I was a lad living in Pennsylvania, we used to obtain

our cultural entertainment by driving to Hershey to attend the

Sunday afternoon concerts at the bandstand in Hershey Park. For

those of you who have been to Hershey Park recently, it was a

much simpler place in my day; no seated ride through the history

of chocolate and various other attractions.

But back to poor Robert. He had been assigned in July of 1991

to assist in the remodeling of the chemistry area of Wilkes

University in Wilkes-Barre, PA. He was soon admitted to a

hospital with flulike symptoms and neurological problems and

was diagnosed as having Guillain-Barre syndrome. After

treatment, he was discharged but got worse at home and finally

ended up being transferred in September of that year to Hershey.

There he was tested for heavy metals but not for thallium, an

element known to cause symptoms of the type Robert was

exhibiting. Robert”s wife Joann visited him regularly and was

quite solicitous of his welfare. On her last visit she made him iced

tea, which she helped him drink, holding his head as by this point

he was virtually paralyzed. Finally, tests for thallium proved

positive and a remedial treatment was started. However, the

treatment came too late and Robert succumbed.

At the university, a number of jars of thallium salts were found.

Various analytical techniques were used to try to determine the

source of Robert”s thallium. One approach was to try to compare

the trace metals in his system with the trace metals in the

university”s thallium salts. Again, as with the DNA tests in the

chipper case, the techniques available at the time were not up to

the task due in this case to the large amount of thallium

interfering with the trace metal analyses. Today, with so-called

ICP-MS (inductively coupled plasma mass spectroscopy) the job

could be done. (Coincidentally, I had never heard of ICP-MS

until a few months ago, when I was asked if the technique was

available at our university. It was my late friend Charlie who

pointed me to a person who was quite competent in this analytical

method.)

By December of 1991, the authorities decided that Robert”s death

was a homicide and they suspected that one of his coworkers at

the university might have spiked the iced tea Robert loved so

well. Indeed, his wife Joann sued the university for not storing

the thallium salts properly and his colleagues were tested for

thallium; none was found. Three years later it was decided to

exhume Robert”s body and Frederic Rieders was called in to do

more tests. He reasoned that the best approach was to look at

Robert”s hair. Hair grows roughly half an inch a month and

Robert”s hair was long enough that Rieders could look back about

a year and a half before Robert died. Sure enough, thallium was

found in the hair, the levels rising and falling over that time

period. But the crowning touch was that just before he died the

level of thallium rose dramatically, indicating that his biggest dose

was ingested while he was in the hospital drinking his wife”s iced

tea. Of course, Joann was indicted but it wasn”t until 1997, 6

years after Robert”s demise that she confessed she had been

adding rat poison to the iced tea starting two months after their

marriage. In those days thallium was used in rat poison and in

depilatories but its use in these products today is not allowed.

So, it wasn”t the thallium from the university at all and if today”s

analytical prowess were available then the case probably would

have been solved sooner. Joann”s confession to a third degree

murder charge, incidentally, spared her a possible death sentence

in a first-degree murder trial. She presumably is now serving a

10- to 20-year sentence.

Back to Henry Lee and O. J. At the symposium Lee showed

pictures of the Simpson-Goldman crime scene that had not been

used in the trial for various reasons. Lee pointed out three bloody

finger marks on Nicole Simpson”s arm, apparently from someone

grabbing her arm. What happened to them? Lee said they were

washed down the drain at the morgue! He also pointed out seven

low-velocity blood drops on her back. Michael Baden, former

chief medical examiner of New York City, said those drops could

not have come from either Nicole nor Ron Goldman but were

probably from the perpetrator. What happened to them? They

too were washed off! Another item not collected was a piece of

paper with blood imprints that was not deemed relevant but that

might have contained fingerprints. Any one of these pieces of

uncollected evidence might have decided the case conclusively.

In the past, when trace evidence was not routinely preserved, it

was common practice for the morgue employees to wash the

body so it would look “nice and clean” for the medical examiner.

Too bad the morgue personnel seem to have been such neatness

freaks in the O. J. case. It might have saved millions or even

billions of person-hours time lost watching the trial! It seems

ironic that much of the talk during the trial dealt with

contamination of the crime scene but I don”t recall mention of

overzealous cleanliness. With the exquisite sensitivity of today”s

analytical techniques for traces of DNA in tissues, toxic

substances, etc. it is obviously a challenge to preserve a crime

scene in its pristine state without contamination or inadvertent

loss of key evidence.

In contrast to this week”s dark subject matter, next week”s topic

will involve light.

Allen F. Bortrum